synthesis germanium functions

Pyridine was used as the solvent and additionally functions as the primary carbon source. In a typical run 1.15g of ferrocene was dissolved in 10 g pyridine, to which 1.0 g of ... Pandurangan A. Morin C. Qian D. Andrews R. Crocker M. 2009 Single-step synthesis of germanium nanowires encapsulated within multi-walled carbon nanotubes. …

The interaction with these diols explains the numerous physiological functions of Ge-132 at low toxicities [52,100]. It was later found that, in solution, ... Understanding this mechanism in depth will enable the purposeful synthesis of novel germanium compounds with a targeted biological activity, yielding more significant and …

We report the single-step synthesis of Ge nanowires encapsulated within multi-walled carbon nanotubes (MWCNTs) from a phenyltrimethylgermane (C 6 H 5 Ge(CH 3) 3) precursor, using a simple chemical vapor deposition (CVD) method.The MWCNT/germanium nanowires were characterized by scanning electron microscopy …

Phylloquinone (vitamin K(1) = VK(1)) and the menaquinones (MK-n, or vitamin K(2) = VK(2)) are naturally occurring forms of VK. Most of the menaquinone series are synthesized by microorganisms, but we have reported that MK-4 is usual in being synthesized by the conversion of orally ingested VK(1) or MK-n in the major tissues of germfree rats and …

Synthesis of germanium/germanium phosphide in-plane heterostructure with efficient photothermal and enhanced photodynamic effects in the second near-infrared biowindow ... Ge is a semiconductor with a work function of 4.8 eV and indirect band gap of ∼ 0.67 eV as well as a direct gap of ∼ 0.8 eV showing unique optical and electronic ...

Abstract Physicochemical properties of stable nanoscale Ge particles have been widely investigated by means of radiation-chemical and chemical-reduction reactions of germanium ions in inversely micellar solutions, as well as various methods for registering the resulting nanoparticles, such as UV–Vis spectrophotometry (measurement of optical …

For comparison, the optimized geometric structures and the calculated work functions for the (1 0 1) surface of CsBr with varying section thicknesses are also shown in Fig. S6.The charge density difference and work function results indicate a charge transfer between CsBr and CsGeBr 3 in CsGeBr 3 /CsBr heterojunction. The position of the …

Synthesis of germanium colloids in low boiling point solvents has also been achieved in this study, by functionalizing germanium nanoparticles with acrylic acid. This step provides oxide-stable propionic acid moiety terminated germanium colloid. Inkjet of germanium nanoparticles on silicon has been explored in further.

A solution-based method is developed for the synthesis of colloidal Ge nanocrystals (NCs), which directly grow from germanium(II) bromide in an oleylamine solution with no extra reducing agents.

Synthesis of zinc germanium oxynitride nanotube as a visible-light driven photocatalyst for NO x decomposition through ordered morphological transformation from Zn 2 GeO 4 nanorod obtained by hydrothermal reaction. ... UV–vis diffuse reflectance spectra converted by Kubelka-Munk function of (Zn 1+ x Ge)(N 2 O x) ...

Semantic Scholar extracted view of "Synthesis of the germanium(II) calixarene {p-Bu8tcalix[8]arene}Ge4 and its reaction with Fe2(CO)9: Generation of the germanium(II)/iron(0) complex {p-Bu8tcalix[8]arene}Ge4[Fe(CO)4]2" by Rebecca A. Green et …

A solution‐based method is developed for the synthesis of colloidal Ge nanocrystals (NCs), which directly grow from germanium(II) bromide in an oleylamine solution with no extra reducing agents. Hybrid photodetectors based on the NCs and poly(3‐hexylthiophene) (P3HT) show promise for large‐area applications, as revealed by …

New oligosilylgermane compounds with weak Ge–H bonds have been used as precursors for the rapid synthesis of germanium (Ge) nanowires in high yields (>80%), via a solution–liquid–solid (SLS) mechanism, using indium (In) nanoparticles as a seeding agent over a temperature range between 180 and 380 °C. Even at low growth …

Finally, we discuss the colloidal synthesis of other germanium-containing compounds, emphasizing technologically relevant germanium chalcogenides that include GeS, GeSe, and GeTe. Original language: English (US) Pages (from-to) 2861-2879: Number of pages: 19: Journal: Chemical Society Reviews: Volume: 42: Issue number: 7:

Using 70-nm-diameter germanium nanospheres as trappable optical probes (GeNTOPs), we could show that kinesin-1 walks with 4-nm-center-of-mass steps. In the long-term, the application of these ...

Self-Seeded Germanium Nanowire Synthesis Methods. Ge nanowires are commonly fabricated by either top-down or bottom-up processes. Each of the …

Germanium (Ge) is one of the critical elements that lack an efficient economic recovery process from dilute sources. An improved catechol-based adsorbent, catechol-functionalized chitosan (C–), was synthesized to recover germanium (Ge) from dilute acidic solutions. The adsorbent was also compared with an N-methylglucamine-based …

Therefore, organic germanium is a kind of "internal Chizhevsky chandelier" [10, 11]. At the same time, organic germanium compounds are nontoxic, they have no side reactions and function in the body for a long time, and hence can be regarded as extremely prom-ising for use in medicine [5, 6]. Dolaychuk et al. [13] reported the results of ...

Understanding this mechanism in depth will enable the purposeful synthesis of novel germanium compounds with a targeted biological activity, yielding …

This Review Article highlights the progress that has been made and insights into the strategies used for the colloidal synthesis of size and shape-controlled germanium nanomaterials and surveys some of the potential applications of these materials in optoelectronics, biological imaging, and energy conversion and storage. Germanium …

A facile size-controlled synthesis (microwave/conventional) of quasi-spherical germanium nanoparticles is reported. Oleylamine serves as a solvent, a binding ligand, and a reducing agent in the synthesis. Reactions were carried out with microwave-assisted heating, and the results have been compared with those produced by …

A profound comprehension of the relevant mechanisms can facilitate the targeted synthesis of new germanium compounds with specific biological …

We present the synthesis and characterization of halide-terminated colloidal Ge nanoparticles of 2–10 nm with a narrow size distribution, synthesized via a novel reaction route. The nanoparticles are prepared by the disproportionation reaction of metastable Ge(I)X solutions and are obtained in a maximum yield of 79%. Control of the nanoparticle …

In recent years, porous aromatic frameworks (PAF) were discovered and their porosity and properties were also explored. They are characterized by a rigid aromatic open-framework structure constructed by covalent …

The synthesis process of germanium compounds frequently demands scrupulous vigilance due to its distinct elemental configuration. This framework …

We report a facile colloidal synthesis of Tin-Germanium (Sn-Ge) heterostructures in the form of nanorods with a small aspect ratio of 1.5-3 and a length smaller than 50nm.

The synthesis process of germanium compounds frequently demands scrupulous vigilance due to its distinct elemental configuration. This framework functions prominently during the extraction stage where impurities are meticulously eliminated without modifying Ge's fundamental properties.

Germanium nanoparticles with an average size of 5 ± 1 nm were synthesized by the room-temperature reduction of GeCl4 in ethylene glycol using a solution of NaBH4 in triglyme. By modifying the reaction conditions, other morphologies can also be accessed, including larger spherical particles and nanocubes.